4. Barcelona 3-2 Real Madrid (Spanish Super Cup, August 2011):

One of the many ill-tempered matches between the Spanish giants, the match was marred by off the pitch incidents. Madrid twice came from behind to level on aggregate, until Messi struck late on to add another trophy to Barcelona’s impressive cabinet. The off the field brawl took place when Marcelo was sent off for a rash challenge on Cesc Fabregas. The matter turned ugly when Real boss Mourinho involved himself in the brawl by poking then Barcelona assistant coach Tito Vilanova in the eye.