Kane
It’s pretty weird to imagine an oversized demon-like Kane standing at the top of the ladder and grabbing Money In The Bank briefcase. But that scene became a reality at the inaugural Money In The Bank PPV in 2010 which also started a new tradition.
Kane was the first superstar to cash-in the briefcase on the same night he won it. After one and a half-hour of winning MITB contract, the Big Red Machine came out with a referee to cash it in on Rey Mysterio who just successfully defended the world title against Jack Swagger.
A helpless Mysterio suffered a Chokeslam followed by a Tombstone Piledriver from Kane who started his only reign with the World Heavyweight Championship, that night.